Lignin-based acrylate adhesive without organic solvent processing

作者:Yan, Yongping; Li, Yao; Han, Ying; Ma, Zihao; Sun, Yanning; Li, Jigeng; Sun, Guangwei*
来源:New Journal of Chemistry, 2023, 47(8): 4086-4094.
DOI:10.1039/d2nj05736k

摘要

As a green adhesive, lignin-based acrylate adhesives have a promising future in substitute commercial adhesives owing to their cost-effectiveness, and environmental friendliness. In this work, a green and convenient strategy for the fabrication of lignin-based acrylate adhesives was developed via the introduction of lauryl methacrylate with a low glass transition temperature (-62 degrees C) into the chemical structure of lignin to improve the compatibility, toughness, strength and wettability of lignin-based adhesives. With the introduction of lauryl methacrylate, the shear strength of the lignin-based adhesive reached 5.10 MPa, which is 114% higher than the traditional acrylate adhesive. Moreover, the lignin-based adhesive also exhibits excellent hydrophobicity and high shear strength after 12 h of immersion in water. This work not only provides a new strategy for the fabrication of economical, green, and sustainable lignin-based acrylate adhesives without the participation of organic solvents, but also achieves the value-added utilization of lignin.

  • 单位
    大连工业大学

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