Ce(SO4)2/α-Fe2O3 selective catalytic reduction of NOx with NH3: preparation, characterization, and performance

作者：Zhou, Huimin; Cheng, Ting; Du, Bo; Zou, Xuehua; Xie, Qiaoqin; Chen, Tianhu; Zhu, Chengzhu^*

来源：Environmental Science and Pollution Research, 2022, 29(56): 84421-84433.

DOI：10.1007/s11356-022-21748-z

• Goethite
• Ce(SO4)(2)
• alpha-Fe2O3
• SCR
• Nitrogen oxides
• SO2 tolerance
• Stability

To achieve a low-cost, high-activity denitrification catalyst with excellent water and sulfur resistance, goethite and Ce(SO4)(2)center dot 4H(2)O were used to prepare Ce(SO4)(2)/alpha-Fe2O3 composite catalyst by the impregnation way and investigated the effect of Ce(SO4)(2) on the properties of goethite. Ce(SO4)(2)/alpha-Fe2O3 with various preparation conditions for denitration was systematically discussed, and its structure and properties were characterized by XRD, BET, TEM, XPS, H-2-TPR, and NH3-TPD methods. The results showed that Ce(SO4)(2)/alpha-Fe2O3 over the Ce/Fe molar ratio of 0.02 and calcination temperature of 350 degrees C had excellent catalytic activity, resistance to sulfur, and water properties and stability. When NOx initial concentration was 500 ppm, gas hourly space velocity was 36,000 h(-1) and its reaction temperature was 300 degrees C; the NOx conversion efficiency was maintained at over 95% along with 300 ppm SO2 and nearly 100% couple with 10% H2O. Its superior performance was mainly attributed to the enhancement of the surface adsorbed oxygen and acidity of alpha-Fe2O3 by cerium sulfate. The multiple advantages of Ce-0.(02)/alpha-Fe2O3(350) made it feasible for practical engineering application.