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Annulation Reaction of Quinoxalin-2(1H)-ones Initiated by Electrochemical Decarboxylation of N-Arylglycines

Cui, Jian-Feng; Zhong, Wei-Qiang; Huang, Jing-Mei*
Science Citation Index Expanded
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摘要

A new methodology for the synthesis of tetrahydroimidazo[1,5-a]quinoxalin-4(5H)-ones has been accomplished through annulation of quinoxalin-2(1H)-ones initiated by electrochemical decarboxylation of N-arylglycines catalyzed by ferrocene. With a pair of oxidative and reductive processes occurring among the substrates and intermediates instead of on the electrodes, the electricity consumption was decreased.

关键词

ORGANIC ELECTROSYNTHESIS DERIVATIVES TRIFLUOROMETHYLATION INHIBITORS