Two new coordination frameworks based on rod-shaped secondary building blocks with five-nodal (3,4,5,6)-connected and (3,5,6)-connected network topologies

作者：Fan Jun; Xiao Tian tian; Zheng Sheng Run; Cai Song Liang; Zhang Wei Guang^*

来源：INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14(7): 1156-1160.

DOI：10.1016/j.inoche.2011.04.012

• 5-Aminoisophthalate
• Metal-organic framework
• Rod-shaped secondary building blocks
• Synthesis
• Luminescence

Two new coordination frameworks, namely, [Zn(2)(aip)(Haip)(2)(H(2)O)(2)]center dot 2H(2)O (1) and [Cu(2)(aip) (H(2)O)(mu(3)-OH)(2)] (2),were synthesized from the corresponding metal salts with 5-aminophthalic acid (H(2)aip) under hydrothermal conditions. They possess interesting 3D architectures constructed from the rod-shaped secondary building blocks with 5-nodal (3, 4, 5, 6)-connected and (3, 5, 6)-connected network topologies, respectively. Moreover, luminescent behaviors of two complexes have been investigated at room temperature and they show the intense blue emissions.

• 单位
  华南师范大学