[{beta-SiNi2W10O36(OH)(2)(H2O)}(4)](24-): a new robust visible light-driven water oxidation catalyst based on nickel-containing polyoxometalate

Authors：Yu, Li; Ding, Yong^*; Zheng, Min; Chen, Hongli; Zhao, Junwei

Source：Chemical Communications, 2016, 52(100): 14494-14497.

DOI：10.1039/c6cc02728h

• ABUNDANT METALS
• ELECTROCATALYST
• COMPLEXES

[{beta-SiNi2W10O36(OH)(2)(H2O)}(4)](24-) (1) was reported as efficient, robust visible light-driven water oxidation catalyst for the first time. Of the reported polyoxometalates containing nickel, 1 shows the best photocatalytic O-2 evolution activity with a TON of 335 and TOF of 1.7 s(-1).

• Institution
  北京化工大学; 兰州大学; 河南大学