[{beta-SiNi2W10O36(OH)(2)(H2O)}(4)](24-): a new robust visible light-driven water oxidation catalyst based on nickel-containing polyoxometalate

摘要

[{beta-SiNi2W10O36(OH)(2)(H2O)}(4)](24-) (1) was reported as efficient, robust visible light-driven water oxidation catalyst for the first time. Of the reported polyoxometalates containing nickel, 1 shows the best photocatalytic O-2 evolution activity with a TON of 335 and TOF of 1.7 s(-1).

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