Transition-metal doped titanium-oxo clusters with diverse structures and tunable photochemical properties

作者:Zheng, Dongchun; Zhao, Xiao-Li; Yan, Xueqi; Xuan, Weimin; Zheng, Qi*; Wang, Lianjun; Jiang, Wan
来源:New Journal of Chemistry, 2022, 46(7): 3083-3086.
DOI:10.1039/d1nj05532a

摘要

A family of transition-metal doped Ti-oxo clusters with diverse core structures have been synthesized. Their photocurrent responses can be tuned by varying the heterometals, and the cobalt-doped cluster exhibits the highest H-2 evolution activity (32.5 mu mol g(-1) h(-1)) with good stability.