Transition-metal doped titanium-oxo clusters with diverse structures and tunable photochemical properties

摘要

A family of transition-metal doped Ti-oxo clusters with diverse core structures have been synthesized. Their photocurrent responses can be tuned by varying the heterometals, and the cobalt-doped cluster exhibits the highest H-2 evolution activity (32.5 mu mol g(-1) h(-1)) with good stability.

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