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Cobalt-Catalyzed Protodeboronation of Aryl and Vinyl Boronates

Li, Ninglin; Xiong, Fuqiang; Gao, Ke*
Science Citation Index Expanded
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摘要

An efficient cobalt-based catalytic system for protodeboronation of various aryl and vinyl boronates is described. The reaction is capable of tolerating a wide range of functional groups. The reaction is also extended to deuterodeboronation with D2O, which provides a potential protocol for the synthesis of regiospecifically deuterated arenes and olefins.

关键词

METAL-FREE PROTODEBORONATION BORONIC ACIDS ARYLBORONIC ACIDS PALLADIUM NANOPARTICLES SELECTIVE DEUTERATION COUPLING REACTIONS DEUTERIUM ALKENES BOND FUNCTIONALIZATION