Au/ZnS/ZnO Photoelectrochemical Sensor for Sensitive and Selective Cd2+ Detection

作者:Tao, Bairui*; Li, Jingli; Tian, Pengbo; Wu, Hao; Miao, Fengjuan*; Zang, Yu; Chu, Paul K.
来源:Journal of the Electrochemical Society, 2022, 169(4): 047512.
DOI:10.1149/1945-7111/ac6395

摘要

Sensitive and selective detection of cadmium ions is important to pollution monitoring and human health. In this work, a photoelectrochemical sensor for Cd2+ composed of Au/ZnS/ZnO modified nickel foam is prepared hydrothermally and by reduction. The materials and electrochemical properties are characterized systematically. The Au/ZnS/ZnO electrode exhibits a linear relationship with Cd2+ concentrations in the range of 0.1 mu M - 100 mu M with a correlation coefficient of 0.9993 in conjunction with a high sensitivity of 158.3 mu A mM(-1) cm(-2). The synergistic structure boasting detection of Cd2+ with high sensitivity and selectivity has broad application prospect in environmental science and pollution control.