Rare earth La single atoms supported MoO3-x for efficient photocatalytic nitrogen fixation

作者：Liu, Xiufan; Luo, Yani; Ling, Cancan; Shi, Yanbiao; Zhan, Guangming; Li, Hao; Gu, Huayu; Wei, Kai; Guo, Furong; Ai, Zhihui^*; Zhang, Lizhi^*

来源：Applied Catalysis B: Environmental , 2022, 301: 120766.

DOI：10.1016/j.apcatb.2021.120766

• Single-atom catalyst
• Rare-earth La
• Photocatalytic nitrogen fixation
• Coordination
• MoO3-x

Herein, we demonstrate that the rare-earth La single catalyst with multi-shell characteristic is an excellent choice for this purpose. By merit of its unsaturated orbitals of La, the single La atom strongly bonds with the two-coordinated lattice oxygen on the oxygen-deficient MoO3-x to form O-2c-La-O-2c coordination. This robust metal-support interaction frees single atoms from detachment or aggregation, and prevents catalyst from deactivation. Meanwhile, the occupied 5d orbitals of La back-donate electrons to the 2 pi* molecular orbitals of adsorbed N-2 that substantially activate the inert N equivalent to N bond towards successive hydrogenation. And single La atom could optimize the electron property of the MoO3-x support to promote photocatalytic nitrogen fixation. Without any sacrificial agents, this single atom La catalyst with a well-designed coordination structure delivers an impressive NH3 production rate of 209.0 mu mol h(-1) g(-1) under visible light, outperforming most reported single atom photocatalysts.

• 单位
  上海交通大学