Alx/HKUST-1 prepared by synthetic exchange as catalyst for reduction of NO by CO at low temperature

作者：Zhang, Li; Zheng, Jia-xiang; Zhang, Chao; Wang, Yu-si; Zeng, Jing; He, Han-bing^*; Yuan, Tie-chui; Qin, Yi-hong; Zheng, Ya-jie

来源：TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, 2022, 32(1): 251-261.

DOI：10.1016/S1003-6326(21)65791-6

• copper-based organic framework
• aluminium doping
• synthetic exchange
• denitration at low temperature
• carbon monoxide

Al-x/HKUST-1((x)=1/24, 1/12, 1/6, 1/3), one of the bimetallic copper-based organic framework materials, was successfully prepared by the synthetic exchange method and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), specific surface area (BET), thermogravimetric analysis (TG), infrared spectra (IR), X-ray photoelectron spectroscopy (XPS), and H-2-temperature programmed reduction (H-2-TPR). The findings indicated that Al-x/HKUST-1 maintained the octahedral morphology of its precursor (HKUST-1). The thermal stability and catalytic reduction ability of HKUST-1 skeleton were improved by doping aluminum (Al3+). Al-1/(2)/HKUST-1 showed the best performance among all samples, with a nitric oxide (NO) conversion rate of 100% at 210 degrees C (50 degrees C lower than that of HKUST-1). The valence kind of Al, Cu, and O in Al-1/(2)/HKUST-1 did not change after the catalytic reaction, but the contents of Al, Cu, and 0 in different forms changed significantly. The catalytic process of the Al-x/HKUST-1 followed a Langmuir-Hinshelwood mechanism.