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Electrochemically promoted decarboxylative borylation of alkyl N-hydroxyphthalimide esters

Dai, Jian-Jun*; Teng, Xin-Xin; Fang, Wen; Xu, Jun; Xu, Hua-Jian*
Science Citation Index Expanded
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摘要

An electrochemically promoted decarboxylative borylation reaction is reported. The reaction proceeds under mild conditions in an undivided cell without use of transition metal- or photo-catalysts. The key feature of the reaction is the compatibility of diboron reagents with the electrochemical conditions. This reaction exhibits broad substrate scope, good functional group tolerability, and easy scalability.

关键词

Electrochemical Decarboxylation Borylation Alkyl boronic esters Redox active esters