Coating dense Silicon Carbide layer on artificial graphites to achieve synergistically enhanced thermal conductivity and electronic insulation of polymer composites

Authors：Huang, Min; Tian, Yexin; Kong, Nizao; Liao, Gen; Ye, Chong; Fu, Liqin; Wen, Bingjie; Jia, Kun; Wang, Shuang^*; Liu, Jinshui; Han, Fei^*

Source：Journal of Applied Polymer Science, 2023, 140(25).

DOI：10.1002/app.53983

• electrical insulation
• lightweight
• SiC coating
• spherical graphite
• thermal conductivity
• thermal interface material

As a potential thermal conductive filler, spherical graphite (SG) has high thermal conductivity, low density, and a good spherical shape structure. However, the poor electrical insulation of SG will seriously limit its application in highly integrated electronic device packaging. Herein, through a simple liquid-solid chemical reaction, the surface of the SG particle is firmly covered by a uniform silicon carbide (SiC) ceramic coating. Subsequently, a polycarbosilane precursor is immersed into the pore channels of the SiC layer and pyrolyzed at a high temperature to densify the coating. As compared to the original SG thermal pad, the SiC-coated SG-derived pad exhibits significantly enhanced electrical insulation and even higher thermal conductivity. As a result, the SiC-coated SG-based composite displays a high thermal conductivity of 3.36 W m(-1) K-1, a satisfactory resistivity of 7.10 x 10(10) ? cm accompanied with a low density of 1.65 g/cm(3). This work could provide the instructional designing protocol of the highly thermal conductive carbon-based particles by coating ceramic layers for potential application in electronic packaging.