Regulating Exposed Facets of Metal-Organic Frameworks for High-rate Alkaline Aqueous Zinc Batteries

作者：Yang, Shuo; Lv, Haiming; Wang, Yanbo; Guo, Xun; Zhao, Lingzhi^*; Li, Hongfei^*; Zhi, Chunyi^*

来源：Angewandte Chemie - International Edition, 2022, 61(47).

DOI：10.1002/anie.202209794

• Aqueous Zinc Batteries
• Facets
• Metal-Organic Frameworks
• Superior Rate Capability

Metal-organic frameworks (MOFs) have drawn growing attention as promising electrode candidates for rechargeable batteries. However, most studies focus on the direct use of MOF electrodes without any modification. Post-synthetic modification, a judicious tool to modify targeted properties of MOFs, has been long-neglected in the field of batteries. Herein, crystal-facet engineering is proposed to design MOF-based electrodes with high capacity and fast electrochemical kinetics. We found that a thermally-modified strategy can regulate the dominant exposed facet of Ni-based MOF (PFC-8). With the optimally exposed facets, the battery exhibited admirable rate capability (139.4 mAh g(-1) at 2.5 A g(-1) and 110.0 mAh g(-1) at 30 A g(-1)) and long-term stability. Furthermore, density functional theory calculations demonstrate that stronger OH- adsorption behaviors and optimized electronic structures induced by the regulated exposed facets boost the electrochemical performance.