科研之友
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摘要
The present study describes a class of "large-but-flexible"Pd-NHC complexes derived from dibenzobarrelene. These complexes havebeen successfully employed in Pd-catalyzed challenging heteroaryl-heteroarylSuzuki-Miyaura cross-coupling reactions under aerobic conditions,exhibiting a general and highly efficient protocol for a range ofchallenging substrates. Additionally, the current protocols were successfullyapplied to the synthesis of valuable functional small molecules andconjugated mesopolymers. These findings have significant implicationsfor the development of novel and efficient catalytic methodologiesin the field of organic and functional material synthesis.
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单位广东药学院
