Flame-retardant and leakage-proof phase change composites based on MXene/polyimide aerogels toward solar thermal energy harvesting

作者：Cao, Yan; Weng, Mengman; Mahmoud, M. H. H.; Elnaggar, Ashraf Y.; Zhang, Li; El Azab, Islam H.; Chen, Ying; Huang, Mina; Huang, Jintao^*; Sheng, Xinxin^*

来源：Advanced Composites and Hybrid Materials, 2022, 5(2): 1253-1267.

DOI：10.1007/s42114-022-00504-4

• MXene
• Phase change materials
• Solar-thermal conversion
• Thermal energy storage
• Flame retardancy

To address the problems of easy leakage and high flammability of phase change materials, a series of innovative leakage-proof phase change composites (PCCs) with excellent solar thermal conversion capability and superior flame retardancy have been successfully developed. Herein, two-dimensional layered MXene nanosheets with excellent solar-thermal conversion effect were first synthesized by etching MAX phase with lithium fluoride and hydrochloric acid solutions. MXene/polyimide (PI) aerogel was then prepared by freeze-drying and thermal imidization after MXene dispersions mixed with poly (amic acid). The MXene/PI aerogels were subsequently impregnated into polyethylene glycol (PEG) by vacuum impregnation to obtain new shape-stable MXene/PI@PEG phase change composites (MPPCCs). Among them, MPPCC-4 exhibits a very high PEG loading capacity (98.1%) and high enthalpy (167.9 J/g), and a relative enthalpy efficiency of 99.8%. When compared to PEG, MPPCC-4 has outstanding flame retardant properties, including a 26.2% lower peak heat release rate and an 11.6% lower total heat release rate. In conclusion, MPPCCs show considerable potential for application in solar energy utilization systems.

• 单位
  广东工业大学