Frustrated Layered Self-Assembly Induced Superlattice from Two-Dimensional Nanosheets

作者:Lu, Huanjun; Zhang, Xiaoyan; Sakurai, Tsuneaki; Li, Xiaohong; Tu, Yingfeng*; Guo, Jun; Seki, Shu; Li, Christopher Y.; Ungar, Goran*; Cheng, Stephen Z. D.
来源:Nano Letters, 2020, 20(12): 8647-8653.
DOI:10.1021/acs.nanolett.0c03352

摘要

Here we reported a hierarchical self-assembly approach toward well-defined superlattices in supramolecular liquid crystals by fullerene-based sphere-cone block molecules. The fullerenes crystallize to form monolayer nanosheets intercalated by the attached soft hydrocarbon cones. The frustration caused by cross-sectional area mismatch between the spheres and the somewhat oversize cones leads to a unique lamellar superlattice whereby each stack of six pairs of alternating sphere-cone sublayers is followed by a cone double layer. While such areal mismatch problems in soft matter are usually solved by interface curvature, the lamellar superlattice solution is best suited to systems with rigid layers. Meanwhile, formation of the superlattice significantly improves the material's transient electron conductivity, with the maximum value being among the highest for it-conjugated organic materials. The design principle of solving steric frustration by forming a superlattice opens a new avenue toward self-assembled optoelectronic materials.

  • 单位
    西安交通大学; 青岛大学; 苏州大学