Mn4+ activated phosphors in photoelectric and energy conversion devices

作者：Ding, Yang; Wang, Chunhua; Pei, Lang; Mao, Qinan; Bandaru, Sateesh; Zheng, Runtian; Maitra, Soumyajit; Liu, Meijiao; Chen, Li-Hua^*; Su, Bao-Lian^*; Zhong, Jiasong^*

来源：Journal of Energy Chemistry, 2023, 86: 277-299.

DOI：10.1016/j.jechem.2023.07.033

• Mn4+ activator
• Phosphor
• Structure tailoring
• Photoelectric device
• Energy conversion

Owing to their high luminous efficiency and tunable emission in both red light and far-red light regions, Mn4+ ion-activated phosphors have appealed significant interest in photoelectric and energy conversion devices such as white light emitting diode (W-LED), plant cultivation LED, and temperature thermometer. Up to now, Mn4+ has been widely introduced into the lattices of various inorganic hosts for brightly red-emitting phosphors. However, how to correlate the structure-activity relationship between host frame-work, luminescence property, and photoelectric device is urgently demanded. In this review, we thoroughly summarize the recent advances of Mn4+ doped phosphors. Meanwhile, several strategies like co-doping and defect passivation for improving Mn4+ emission are also discussed. Most importantly, the relationship between the protocols for tailoring the structures of Mn4+ doped phosphors, increased luminescence performance, and the targeted devices with efficient photoelectric and energy conversion efficiency is deeply correlated. Finally, the challenges and perspectives of Mn4+ doped phosphors for practical applications are anticipated. We cordially anticipate that this review can deliver a deep comprehension of not only Mn4+ luminescence mechanism but also the crystal structure tailoring strategy of phosphors, so as to spur innovative thoughts in designing advanced phosphors and deepening the applications.

• 单位
  武汉理工大学