Modification of g-C3N4 with hydroxyethyl cellulose as solid proton donor via hydrogen bond to enhance H2O2 production

作者：Zhang, Pengyan; Zhang, Jing; Wang, Dandan; Zhang, Fan; Zhao, Yuting; Yan, Mengqin; Zheng, Chuanrong; Wang, Qinqin; Long, Mingce; Chen, Chao^*

来源：Applied Catalysis B: Environmental , 2022, 318: 121749.

DOI：10.1016/j.apcatb.2022.121749

• Graphitic carbon nitride
• Hydroxyethyl cellulose
• Hydrogen peroxide
• Intermolecular hydrogen bond
• Solid proton donor

Hydroxyethyl cellulose (HEC) is used as a solid proton donor to modify graphitic carbon nitride (g-C3N4 ) via non -covalent bonds to improve H2O2 production performance. The modified g-C3N4 (CN/HEC) is prepared by stirring the suspension of g-C3N4 and HEC at room temperature and drying. The H2O2 production efficiency of CN/HEC is 3.89 times that of g-C3N4 . Both experimental results and density functional theory calculations (DFT) suggest charge transfer from HEC to g-C3N4 and hydrogen bond formation between HEC and g-C3N4 . CN/HEC possesses higher charge separation efficiency than g-C3N4 . Stability test, XPS, FTIR, and DFT analyses suggest that HEC acts as a proton donor. The synergy of charge separation enhancer and proton donor from HEC promotes the sequential two-step single-electron O2 reduction for H2O2 production. This study explores a way to utilize cellulose material as solid proton donors to modify g-C3N4 via hydrogen bonds under mild conditions for increased H2O2 production performance.

• 单位
  上海交通大学