Amino functionalized carbon nanotubes supported CoNi@CoO-NiO core/shell nanoparticles as highly efficient bifunctional catalyst for rechargeable Znair batteries

摘要

Oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) are the core reaction processes of rechargeable Zn-air battery (ZAB) cathode. Therefore, exploring a bifunctional catalyst with excellent electrochemical performance, high durability, and low cost is essential for rechargeable ZAB. In this work, amino functionalized carbon nanotubes supported core/shell nanoparticles composed of CoNi alloy core and CoO-NiO shell (CoNi@CoOeNiO/NH2-CNTs-1) is synthesized through a simple and efficient hydrothermal reaction and calcination method, which shows higher ORR/ OER bifunctional catalytic performance than the single metal-based catalyst, such as Ni@NiO/NH2-CNTs and Co@CoO/NH2-CNTs. The fabricated bimetallic alloy based catalyst CoNi@CoO-NiO/NH2CNTs-3 with the optimized loading content of CoNi@CoO-NiO core/shell nanoparticles, presents the best bifunctional catalytic performance for ORR/OER. Experimental studies reveal that CoNi@CoOeNiO/NH2-CNTs-3 exhibits the onset potential of 0.956 V and 1.423 V vs. RHE for ORR and OER, respectively. It also exhibits a low overpotential of 377 mV to achieve a 10 mA cm(-2) current density for OER, and positive half-wave potentials of 0.794 V for ORR. And the potential difference between half-wave potential of ORR (E1/2) and the potential at 10 mA cm(-2) for OER (Ej(10)) is 0.813 V. In addition, when CoNi@CoOeNiO/NH2CNTs-3 is used as an air electrode catalyst of rechargeable ZAB, its maximum power density and open circuit voltage (OCV) can reach 128.7 mW cm(-2) and 1.458 V (The commercially available catalyst of Pt/CeRuO2 is 88.1 mW cm(-)2), which strongly demonstrates that the fabricated catalyst CoNi@CoOeNiO/NH2-CNTs-3 can be used as a highly efficient bifunctional catalyst for ZABs, and is expected to replace those expensive precious metal electrocatalysts to meet the growing demand for new energy devices.

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