Boosting photocatalytic H2 generation by assembling a copper complex and carbon nanotubes onto a carbon nitride polymer

作者：Zhang, Jun-Shuai; Zhou, Wen-Chen; Lai, Jia-Yu; Zhang, Wei-De^*

来源：Catalysis Science & Technology, 2023, 13(16): 4765-4773.

DOI：10.1039/d3cy00493g

• HYDROGEN-EVOLUTION
• METAL-FREE
• ARTIFICIAL PHOTOSYNTHESIS
• MOLECULAR CATALYST
• G-C3N4 NANOSHEETS
• CHARGE-TRANSFER
• GRAPHITIC C3N4
• WATER
• SEMICONDUCTORS
• REDUCTION

Solar-driven water splitting is a potential way to solve environmental contamination and the energy crisis on our planet, and is also of great significance for contemporary energy research. Herein, an affordable photocatalyst for boosting H-2 generation was prepared by assembling a copper complex (CuL) and carbon nanotubes (CNTs) onto a carbon nitride polymer (CN). Introduction of both CuL and CNTs promotes separation of photogenerated charge carriers rapidly and enhances optical absorption of the prepared catalyst. What is more, a suitable amount of CuL on CN can work as a substitute for precious metal cocatalysts to decrease the H-2-evolving overpotential. Due to the synergistic effect of CuL and CNTs, the optimized 3CuL/CNTs/CN photocatalyst displays an efficient H-2 evolution rate of 931 & mu;mol g(-1) h(-1) in TEOA aqueous solution, which is much higher than those of 3CuL/CN (487 & mu;mol g(-1) h(-1)) and CN (null). The novel strategy provided in this study could be a way for establishing sustainable and inexpensive photocatalytic systems towards boosting H-2 generation.