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Electrochemical synthesis of α,α-dihaloacetophenones from terminal alkyne derivatives

Zhibin Li; Qi Sun; Peng Qian; Kangfei Hu; Zhenggen Zha; Zhiyong Wang
万方
中国科学院

摘要

By virtue of electrochemistry,a series of α,α-dihaloacetophenones were easily obtained with good to excellent yields.This electrochemical procedure was taken in a divided cell with constant current in aqueous media.The reaction can be carried out smoothly at room temperature under metal and oxidant free condition,which provides an eco-friendly synthesis for the α,α-dihαloacetophenone derivatives.

关键词

Electrochemistry Alkyne derivatives α α-Dihaloacetophenones Divided cell Oxidant free