Novel and highly efficient electro-catalytic cycloaddition of CO2 and epoxides to cyclic carbonates over reusable ionic liquid-based cooperative catalytic system

作者：Hu, Yu Lin^*; Liu, Xiao Bing^*; Rong, Qi

来源：Green Chemistry Letters and Reviews, 2023, 16(1): 2163192.

DOI：10.1080/17518253.2022.2163192

• Ionic liquid electrolyte
• carbon dioxide
• epoxides
• electro-catalytic carboxylation
• sustainable electro-synthesis

A novel and highly efficient electro-catalytic protocol for the synthesis of cyclic carbonates from epoxides and CO2 using 1-aminopropyl-3-methylimidazolium dicyanamide ([APMIm]DCA) as the supporting electrolyte, graphite as the anode, and Ti/TiO2-CNT-Pt as the cathode has been developed. Based on the cooperative effect between active Ti/TiO2-CNT-Pt cathode and active sites of supporting ionic liquid electrolyte [APMIm]DCA, CO2 and epoxides could be effectively converted into the corresponding cyclic carbonates in high to excellent yields under mild conditions. Moreover, the electro-catalytic system could be easily recovered and reused for six successive cycles without a considerable decrease in catalytic activity. This work provides a sustainable and efficient cooperative strategy for the chemical fixation of carbon dioxide into valuable cyclic carbonates.