Multifunctional magnetic MgMn-oxide composite for efficient purification of Cd2+ and paracetamol pollution: Synergetic effect and stability

作者：Chen, Meiqing; Liu, Juan; Bi, Yingzhi; Rehman, Saeed; Dang, Zhi; Wu, Pingxiao^*

来源：Journal of Hazardous Materials, 2020, 388: 122078.

DOI：10.1016/j.jhazmat.2020.122078

• Cadmium
• Pharmaceutical
• Magnetic material
• Metals synergy
• Removal

A multifunctional magnetic composite (0.3Ma-MgMnLDO-a) with the function of Cd2+ adsorption and paracetamol (PAM) degradation was successfully fabricated. Surface morphology showed that Fe3O4 agglomeration was overcome on composite. The composite had high specific surface area of 105.32 m(2) g(-1) and saturation magnetization of 40 emu.g(-1). 0.3Ma-MgMnLDO-a could reach Cd2+ adsorption equilibrium within 5 min with 99 % removal rate. The maximum adsorption capacity was 3.76 mmol.g(-1) (422.62 mg g(-1)), which apparently higher than that of Fe3O4-a and MgMnLDO-a, indicating that the Fe/Mn synergism results in excellent ability for Cd2+ adsorption. Moreover, the composite could efficiently activate peroxymonosulfate (PMS) to rapid degrade PAM with the highest first-order rate constants (k(obs) = 0.116 min(-1)) and total organic carbon (TOC) removal rate (67.7 %), which also due to the contribution of Fe/Mn synergism in PMS activation. The cycling of Mn-III/Mn-IV and Fe-II/Fe-III played an important role in activating PMS to generateO(2)(center dot-), O-1(2) and (OH)-O-center dot for degradation. The composite exhibited both stable adsorption and catalytic performance on wide pH (3-9) and five reuse cycles. Notably, there was mutual promotion between Cd2+ and PAM adsorption, while the coexistence of Cd2+ had slight inhibition on PAM degradation. Overall, the magnetic composite had promising application for purifying heavy metals and pharmaceuticals.