An all-solid-state carbon-air battery reaching an output power over 10 W and a specific energy of 3600 Wh kg-1

作者：Yan, Xiaomin; Zhou, Mingyang; Zhang, Yapeng; Qiu, Qianyuan; Chen, Qianyang; Cai, Weizi; Tang, Yubao; Liu, Jiang^*

来源：Chemical Engineering Journal, 2021, 404: 127057.

DOI：10.1016/j.cej.2020.127057

• Carbon-air battery
• All-solid-state
• Tubular 3-battery-stack
• Improved current collection
• Mechanically rechargeable

Carbon-air batteries have a very high theoretical specific energy. However, they have not been given sufficient attention because of the challenges associated with optimizing the battery design and making it rechargeable. Here we report a novel carbon-air battery stack based on solid oxide electrolyte which enables high operating temperature. The battery is composed of a tubular membrane electrode assembly (MEA), with a solid oxide electrolyte layer sandwiched between two porous electrodes, and carbon powder filled inside the MEA tube. By introducing a row of holes along the length direction of the MEA tube for current collection, the performance of the battery can be significantly enhanced because of shortened current paths. By using a removable quartz plug to stuff the open end of the MEA tube, the battery becomes mechanically rechargeable. Several batteries can be assembled into a stack by connecting the batteries in electrical series through the holes for current collection. A 3-battery-stack operating at 800 degrees C displays an output power of 11.0 W, corresponding to similar to 160 mW cm(-2). With an overall carbon powder of similar to 10 g, the stack discharges at 0.5 A and similar to 2.75 V for 26 h, revealing a specific energy of similar to 3600 Wh kg(-1), which is significantly higher than those of the state-of-the-art metal-air batteries.

• 单位
  华南农业大学; 1